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A magnet is a material that can exert a noticeable force on other materials without actually contacting them. This force is known as a magnetic force and may either attract or repel. While all known materials exert some sort of magnetic force, it is so small in most materials that it is not readily noticeable. With other materials, the magnetic force is much larger, and these are referred to as magnets. The Earth itself is a huge magnet.

Some magnets, known as permanent magnets, exert a force on objects without any outside influence. The iron ore magnetite, also known as lodestone, is a natural permanent magnet. Other permanent magnets can be made by subjecting certain materials to a magnetic force. When the force is removed, these materials retain their own magnetic properties. Although the magnetic properties may change over time or at elevated temperatures, these materials are generally considered to be permanently magnetized, hence the name.

When making magnets, the raw materials are often more important than the manufacturing process. The materials used in permanent magnets (sometimes known as hard materials, reflecting the early use of alloy steels for these magnets) are different than the materials used in electromagnets (some-times known as soft materials, reflecting the use of soft, malleable iron in this application).

Permanent magnet lodestones contain magnetite, a hard, crystalline iron ferrite mineral that derives its magnetism from the effect the earth's magnetic field has on it. Various steel alloys can also be magnetized. The first big step in developing more effective permanent magnet materials came in the 1930s with the development of Alnico alloy magnets. These magnets take their name from the chemical symbols for the aluminum-nickel-cobalt elements used to make the alloy. Once magnetized, Alnico magnets have between 5 and 17 times the magnetic force of magnetite.

Ceramic permanent magnets are made from finely powdered barium ferrite or strontium ferrite formed under heat and pressure. Their magnetic strength is enhanced by aligning the powder particles with a strong magnetic field during forming. Ceramic magnets are comparable to Alnico magnets in terms of magnetic force and have the advantage of being able to be pressed into various shapes without significant machining.

Flexible permanent magnets are made from powdered barium ferrite or strontium ferrite mixed in a binding material like rubber or a flexible plastic like polyvinyl chloride.

In the 1970s, researchers developed permanent magnets made from powdered samarium cobalt fused under heat. These magnets take advantage of the fact that the arrangement of the groups of atoms, called magnetic domains, in the hexagonal crystals of this material tend to be magnetically aligned. Because of this natural alignment, samarium-cobalt magnets can be made to produce magnetic forces 50 times stronger than magnetite. Headphones for small, personal stereo systems use samarium-cobalt permanent magnets. Samarium-cobalt magnets also have the advantage of being able to operate in higher temperatures than other permanent magnets without losing their magnetic strength.

Similar permanent magnets were made in the 1980s using powdered neodymium iron boron which produces magnetic forces almost 75 times stronger than magnetite. These are the most powerful permanent magnets commercially available today.

Electromagnet Materials

Pure iron and iron alloys are most commonly used in electromagnets. Silicon iron and specially treated iron-cobalt alloys are used in low-frequency power transformers.

A special iron oxide, called a gamma iron oxide, is often used in the manufacture of magnetic tapes for sound and data recording. Other materials for this application include

The above illustrations show a typical powdered metallurgy process used to produce powerful neodymium-iron-boron permanent magnets.
The above illustrations show a typical powdered metallurgy process used to produce powerful neodymium-iron-boron permanent magnets.

cobalt-modified iron oxides and chromium dioxide. The material is finely ground and coated on a thin polyester plastic film.

Other Magnetic Materials

Magnetic fluids can be made by encapsulating powdered barium ferrite particles in a single layer of molecules of a long-chain polymer plastic. The particles are then held in suspension in a liquid like water or oil. Because of the plastic encapsulation, the magnetic particles slide over each other with almost no friction. The particles are so small that normal thermal agitation in the liquid keeps the particles from settling. Magnetic fluids are used in several applications

Magnet

as sealants, lubricants, or vibration damping materials.

The Manufacturing 
Process

Just as the materials are different for different kinds of magnets, the manufacturing processes are also different. Many electromagnets are cast using standard metal casting techniques. Flexible permanent magnets are formed in a plastic extrusion process in which the materials are mixed, heated, and forced through a shaped opening under pressure.

Some magnets are formed using a modified powdered metallurgy process in which finely powdered metal is subjected to pressure, heat, and magnetic forces to form the final magnet. Here is a typical powdered metallurgy process used to produce powerful neodymium-iron-boron permanent magnets with cross-sectional areas of about 3-10 square inches (20-65 sq cm):

Preparing the powdered metal

  • 1 The appropriate amounts of neodymium, iron, and boron are heated to melting in a vacuum. The vacuum prevents any chemical reaction between air and the melting materials that might contaminate the final metal alloy.
  • 2 Once the metal has cooled and solidified, it is broken up and crushed into small pieces. The small pieces are then ground into a fine powder in a ball mill.

Pressing

  • 3 The powdered metal is placed in a mold, called a die, that is the same length and width (or diameter, for round magnets) as the finished magnet. A magnetic force is applied to the powdered material to line up the powder particles. While the magnetic force is being applied, the powder is pressed from the top and bottom with hydraulic or mechanical rams to compress it to within about 0.125 inches (0.32 cm) of its final intended thickness. Typical pressures are about 10,000 psi to 15,000 psi (70 MPa to 100 MPa). Some shapes are made by placing the powdered material in a flexible, air-tight, evacuated container and pressing it into shape with liquid or gas pressure. This is known as isostatic compaction.

Heating

  • 4 The compressed "slug" of powdered metal is removed from the die and placed in an oven. The process of heating compressed powdered metals to transform them into fused, solid metal pieces is called sintering. The process usually consists of three stages. In the first stage, the compressed material is heated at a low temperature to slowly drive off any moisture or other contaminants that may have become entrapped during the pressing process. In the second stage, the temperature is raised to about 70-90% of the melting point of the metal alloy and held there for a period of several hours or several days to allow the small particles to fuse together. Finally, the material is cooled down slowly in controlled, step-by-step temperature increments.

Annealing

  • 5 The sintered material then undergoes a second controlled heating and cooling process known as annealing. This process removes any residual stresses within the material and strengthens it.

Finishing

  • 6 The annealed material is very close to the finished shape and dimensions desired. This condition is known as "nearnet" shape. A final machining process removes any excess material and produces a smooth surface where needed. The material is then given a protective coating to seal the surfaces.

Magnetizing

  • 7 Up to this point, the material is just a piece of compressed and fused metal. Even though it was subjected to a magnetic force during pressing, that force didn't magnetize the material, it simply lined up the loose powder particles. To turn it into a magnet, the piece is placed between the poles of a very powerful electromagnet and oriented in the desired direction of magnetization. The electromagnet is then energized for a period of time. The magnetic force aligns the groups of atoms, or magnetic domains, within the material to make the piece into a strong permanent magnet.